---
title: Putting MOFs in Numbers - an Infografic | novoMOF
description: Have a look at our metal-organic frameworks infografic from a numbers perspective. From first discovery, early research to properties and applications.
image: https://blog.novomof.com/hubfs/Imported_Blog_Media/Header_Putting_MOFs_in_Numbers.jpg
---

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# Putting MOFs in Numbers - an Infografic

By [Niklas](https://blog.novomof.com/author/niklas) 25. November 2019 [General](https://blog.novomof.com/tag/general)

- [No Comments](https://blog.novomof.com/blog/putting-mofs-in-numbers-an-infografic#comments-listing)

We took a different perspective on metal-organic frameworks and put together an infografic about these materials. Enjoy!

Updated Version now online – 16.12.2019

Click on the infografic for a high-res version.

 

[![Updated Version: Putting MOFs in Numbers - Infografic](https://blog.novomof.com/hs-fs/hubfs/Imported_Blog_Media/Putting_MOFs_in_Numbers_Infografic_updated_web-scaled.jpg?width=513&height=2560&name=Putting_MOFs_in_Numbers_Infografic_updated_web-scaled.jpg)](https://blog.novomof.com/hubfs/Imported_Blog_Media/Putting_MOFs_in_Numbers_Infografic_updated_web.png)

How did you like this infografic? Let us know below in the comments!

 

 

[![CTA_Call_Daniel](https://blog.novomof.com/hs-fs/hubfs/CTA_Call_Daniel.png?width=502&name=CTA_Call_Daniel.png)](https://info.novomof.com/cs/c/?cta_guid=8e17ab32-e4ea-4a81-b493-e11d3ef96816&signature=AAH58kHMViZNQ9I0X1MVw99QVAM3ttbJaQ&placement_guid=d821bfb2-80a4-4df7-b8c6-af53ba016265&canon=https%3A%2F%2Fnovomof.com%2Fblog%2Fputting-mofs-in-numbers-an-infografic%2F&portal_id=5529658&contentType=blog-post&__hstc=30035104.384c7082399724a141c902fe43b53459.1605263846213.1605263846213.1605263846213.1&__hssc=30035104.1.1605263846213&__hsfp=2406870324&hsutk=384c7082399724a141c902fe43b53459)

 

## The research

First of three publications by A.F. Wells about molecular and polymeric frameworks, describing existing and theoretical structures in terms of networks:

Wells, A. F.(1977). Three-dimensional nets and polyhedra. (1978). Acta Cryst. B34, 2958 [doi.org:10.1107/S0567740878009814](https://doi.org/10.1107/S0567740878009814)

First description of porous coordination polymers by Richard Robson:

Hoskins, B. F., & Robson, R. (1989). Infinite polymeric frameworks consisting of three dimensionally linked rod-like segments. Journal of the American Chemical Society, 111(15), 5962–5964. [doi:10.1021/ja00197a079](https://pubs.acs.org/doi/abs/10.1021/ja00197a079)

First publication by Omar Yaghi featuring ‘metal-organic frameworks’ in the title and thus coining the term:

OM Yaghi, H Li (1995). Hydrothermal synthesis of a metal-organic framework containing large rectangular channels. Journal of the American Chemical Society 117 (41), 10401-10402. doi:[10.1021/ja00146a033](https://doi.org/10.1021/ja00146a033)

Publication by Omar Yaghi demonstrating permanent porosity of MOFs and start of wide research into this class of materials:

Li, H., Eddaoudi, M., O’Keeffe, M. et al. (1999). Design and synthesis of an exceptionally stable and highly porous metal-organic framework. Nature 402, 276–279. doi:[10.1038/46248](https://www.nature.com/articles/46248)

The research on metal-organic frameworks has steadily increased in the period between 1995 and 2019. There are more than [456’000 search results related to the search term “metal-organic framework”](https://scholar.google.com/scholar?hl=de&as_sdt=0%2C5&q=%22metal-organic+framework%22&oq=%22metal-organic) on Google Scholar.

### Top10 authors

The top 10 authors in the field of metal-organic frameworks are:

1. Omar M. Yaghi
2. Omar K. Farha
3. Joseph T. Hupp
4. Hong-Cai Zhou
5. Michael O’Keeffe
6. Banglin Chen
7. Jeffrey R. Long
8. Wenbin Lin
9. Mohamed Eddaoudi
10. Christian Serre

The data on publications on [“metal-organic frameworks” and the top10-authors can be found at microsoft.academics.com](https://academic.microsoft.com/topic/179366358).

### Most cited publication

The publication by Kitagawa, Kitaura and Noro on ‘[Functional porous coordination polymers](https://doi.org/10.1002/anie.200300610)‘ has been cited 9’523 times (according to [academics.microsoft.com](https://academic.microsoft.com/paper/1999937609/citedby/search?q=Functional%20porous%20coordination%20polymers&qe=RId%253D1999937609&f=&orderBy=0)), making it the most cited publication on metal-orrganic frameworks.

Omar Yaghi, the pioneer of MOFs, is not far off with 7’658 citations of his publication [‘Reticular synthesis and the design of new materials’ (2003).](https://www.nature.com/articles/nature01650)

Metal-organic frameworks are research on 7 continents, in more than 250 research institutes by more than 1000 researchers. These porous materials even haave two dedicated conferences per year: [EuroMOF20XX](https://euromof2019.sciencesconf.org/) and [MOF20XX.](https://dechema.de/en/MOF2020.html)

## The Material

Metal-organic frameworks are made by combining metal ions with organic linkers (ligands). There are 86+ usable metals and more than a 1000 possible ligands. More than 5 different methods of synthesis are available.

More than 81’000 MOF-structures are documented in the [Cambridge Structural Database](https://www.ccdc.cam.ac.uk/). That’s 330x the number of documented zeolite structures.

### Crystallinity

Not all MOFs are created equally – [amorphous MOFs](https://pubs.acs.org/doi/10.1021/ar5000314) miss the periodic order.

### Multi-dimensional pores

MOFs feature 1-, 2-, or 3-dimensional pores, that can be used for a variety of applications.

### Maximum number of metals

Up to 10 different metal ions have been synthesised into one MOF-74 structure (Mg, Ca, Sr, Ba, Mn, Fe, Co, Ni, Zn and Cd).

### Material properties

The [largest documented surface area in 1 gram of MOF](https://onlinelibrary.wiley.com/doi/10.1002/anie.201808240) was reported for DUT-60 with 7’839 m2. The absolute stability limits were calculated to be at 10’577 m2/g.

The largest pore size is documented for IRMOF-74 reaching 98 Angstrom.

Particles are up to 10’000nm large (NU-1003), the smallest are reported for HKUST-1 at 1.6 nm. ZIF-51 has the smallest average particle size at 41.6 nm.

MOFs have very specific properties:

- Adsorption
- Desorption
- Encapsulation
- Filtration
- Catalysis
- Luminescence
- Bio-mimetics
- Isolation
- Electroconducting

### Industry applications

These can be used in various industrial applications such as

- Gas Adsorption
- Gas Purification
- Gas Storage
- Hydrogen Catalysis
- Biomedical Imaging and Sensing
- Semiconductors
- Drug Delivery Systems
- Carbon Capture
- Dehumidification
- Detection and Sensing
- Nerve Gas Degradation
- Water Treatment
- Air Filtration
- Shelf life management
- Fart-proof Underwear
- Bio-mimetic Mineralisation
- Toxic Gas Capture
- Desalinatiion
- Amelioration of Goods
- Contaminent Removal

+ many more opportunities.

 

 

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### *Author* Niklas

[More posts by Niklas](https://blog.novomof.com/author/niklas)

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